Ellipsometric characterization of inhomogeneous non-stoichiometric silicon nitride films

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Authors

NEČAS David FRANTA Daniel OHLÍDAL Ivan PORUBA Aleš WOSTRÝ Petr

Year of publication 2013
Type Article in Periodical
Magazine / Source Surface and Interface Analysis
MU Faculty or unit

Central European Institute of Technology

Citation
Web http://onlinelibrary.wiley.com/doi/10.1002/sia.5250/abstract
Doi http://dx.doi.org/10.1002/sia.5250
Field Optics, masers and lasers
Keywords optical characterization; variable-angle spectroscopic ellipsometry; phase-modulated ellipsometry; inhomogeneous films; silicon nitride films
Attached files
Description Variable-angle spectroscopic ellipsometry is employed for the optical characterization of non-stoichiometric silicon nitride thin films exhibiting inhomogeneity formed by refractive index and extinction index changes through the film thickness. For all the film samples, the best fit of the experimental data is achieved if, in addition to the inhomogeneity, an overlayer or roughness of the upper boundary is included. However, distinguishing of these two defects is found not to be possible. The influence of working gas ratio, deposition temperature and on/off time on the film properties is studied. The refractive index and extinction coefficient is found to increase with increasing working gas ratio and less significantly with decreasing deposition temperature. It is also found that the inhomogeneity increases with decreasing deposition temperature, and the deposition rate of the films decreases with increasing working gas ratio. The influence of the on/off time on the film properties is practically unimportant.
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