Phenanthrylene-butadiynylene and Phenanthrylene-thienylene Macrocycles: Synthesis, Structure, and Properties
| Authors | |
|---|---|
| Year of publication | 2016 |
| Type | Article in Periodical |
| Magazine / Source | Journal of Organic Chemistry |
| MU Faculty or unit | |
| Citation | |
| Web | http://pubs.acs.org/doi/abs/10.1021/acs.joc.6b00814 |
| Doi | http://dx.doi.org/10.1021/acs.joc.6b00814 |
| Field | Organic chemistry |
| Keywords | SHAPE-PERSISTENT MACROCYCLES; ARYLENE-ETHYNYLENE MACROCYCLES; HYDROCARBON CHAIN-LENGTH; CONJUGATED MACROCYCLES; SPECTROSCOPIC PROPERTIES; PHOTOPHYSICAL PROPERTIES; ORGANIC MATERIALS; BUILDING-BLOCKS |
| Description | A series of macrocycles consisting of 9,10-substituted phenanthrenes connected by butadiynylene linkers in positions 3 and 6 has been described as well as their transformation into the corresponding phenanthrylene-thienylene macrocycles. Structure and properties of the macrocycles, such as self-association in solution and optical and electrochemical properties, were studied and reported in a comparative manner with respect to the effects of the different sizes and shapes of the macrocycles and the character and length of their side chains. |
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