The Mystery of Guanine Oxidation Double Peak

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Authors

VEČEŘOVÁ Aneta TŘÍSKOVÁ Iveta TRNKOVÁ Libuše

Year of publication 2017
Type Article in Proceedings
Conference XXXVII. Moderní elektrochemické metody
MU Faculty or unit

Faculty of Science

Citation
Web https://www.bestservis.eu/upload/file/Sbornik_metody17.pdf
Field Physical chemistry and theoretical chemistry
Keywords guanine; oligonucleotides; mercury electrode; voltammetry; chronoamperometry
Description Chemical reversible oxidation of guanine moieties after their previous reduction on a mercury electrode gives under certain conditions rise to voltammetric double peak. The origin of this signal, entwined with many questions, is still unknown. The aim of this work is to indicate the answers of these questions by systematically led voltammetric experiments which evaluate the electrochemical nature of guanine oxidation double peak (GODP) in short oligonucleotides (ONs).
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