Detekce těkavých a částečně těkavých meziproduktů a produktů elektrochemických procesů hmotnostní spektrometrií
Title in English | Detection of volatile and semivolatile intermediates and poducts of electrochemical processes by means of mass spectrometry |
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Authors | |
Year of publication | 2000 |
Type | Article in Proceedings |
Conference | Proceedens of the 18th Informal Meeting on Mass Spectrometry |
MU Faculty or unit | |
Citation | |
Field | Electrochemistry |
Keywords | DEMS mass spectrometry electrochemistry aromatic hydrocarbons adsorption |
Description | The presentation describes possible on-line connection of electrochemical cell and mass spectrometer, used for detection, identification and observation in time of volatile and semivolatile species during electrochemical polarisation of working electrode. As a trial system we studied the process of electrochemical hydrogenation of naphthalene and benzene in 0.5M sulphuric acid on polycristalline Pt electrode. Beside the hydrogenated products the parent hydrocarbons after desorption were detected. |
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