Regioselektivita a vliv chirální pomocné látky vázané na dipolu na enantioselektivitu 1,3-dipolární cykloadice

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Title in English Regioselectivity and influence of chiral auxiliary bound on dipol upon enantioselectivity of 1,3-dipolar cycloaddition
Authors

TRÁVNÍČEK Martin POTÁČEK Milan

Year of publication 2001
Type Article in Proceedings
Conference Sborník XXV. Konference organických chemiků
MU Faculty or unit

Faculty of Science

Citation
Field Organic chemistry
Keywords enantioselectivity; regioselectivity; chiral auxiliary; 1;3-dipolar cycloaddition; azomethine ylides
Description Azomethine ylides based on phenanthridinium skeleton with bound chiral auxiliary were followed in 1,3-dipolar cycloaddition with dipolarophiles. Regioselectivity and enantioselectivity in the reaction was evaluated by COSY and HMBC NMR experiments as well as by HPLC with nonracemic sorbent on detector CD Jasco.
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