Reakce betainů kyseliny fluorofosforečné s protickými nukleofily.

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Title in English	Reactions of fluorophosphoric acid betaines with protic nucleophiles.
Authors	SLUKA Radek VAVŘÍKOVÁ Karla ČERNÍK Miloš
Year of publication	2001
Type	Article in Proceedings
Conference	53. zjazd chemických spoločností. Sborník prispevkov 2.
MU Faculty or unit	Faculty of Science
Citation
Field	Inorganic chemistry
Keywords	Betaines; Fluorophosphoric acid; Protic nucleophiles; Amidofluorophosphates
Description	The hydrolysis and ammonolysis of fluorophosphoric acid betaines of the type B.PO2F was studied by 19F and 31P NMR spectroscopy. The main product of the hydrolysis is the 1,2-difluorodiphosphate, while the ammonolysis furnishes the amidofluoro- phosphate. Its condensation with betaine gives a hitherto unknown imido- 1,2-difluorodiphosphate, which is isoelectronic with above mentioned 1,2-difluorodiphosphate.
Related projects:	Structure and character of bonding, properties and analysis of synthetic and natural molecular ensembles