Bis(difluorooxoiodonium)Selenate.

Investor logo
Investor logo

Warning

This publication doesn't include Faculty of Arts. It includes Faculty of Science. Official publication website can be found on muni.cz.
Authors

ŽÁK Zdirad ČERNÍK Miloš

Year of publication 1997
Type Article in Proceedings
Conference 17th European Crystallographic Meeting. Book of Abstracts.
MU Faculty or unit

Faculty of Science

Citation
Field Inorganic chemistry
Keywords Bis(difluorooxoiodonium)Selenate; Synthesis; Crystal structure
Description Bis(difluorooxoiodonium)Selenate.The title compound has been prepared by reaction of iodine pentafluoride with (SeO3)4. Its X-ray single crystal structure analysis revealed a rather covalent than ionic structure with an F2(O)IOSeO2OI(O)F2 molecule. Due to unsaturated coordination of I(V) atoms, every molecule is linked via 4 relatively strong SeO...I interactions to its two nearest neighbours forming corrugated eight-membered rings. These rings are joined by common Se(VI) spiroatoms into infinite chains.
Related projects:

You are running an old browser version. We recommend updating your browser to its latest version.