Synthesis of Heterocyclic Skeletons by the Reaction of N1-(2-Cyanophenyl)-benzimidoyl Chloride with Thioamides

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Authors

MOHAMED Walid Fathalla PAZDERA Pavel

Year of publication 2002
Type Article in Periodical
Magazine / Source Molecules
MU Faculty or unit

Faculty of Science

Citation
Field Organic chemistry
Keywords N1-(2-cyanophenyl)-benzimidoyl chloride; thioamide; 3;1-benzo-thiazine; 1;3;5-benzotriazocine; quinazoline; imidoyl chlorides; N-imidoyl thioureas.
Description The reaction of N1-(2-cyanophenyl)-benzimidoyl chloride with reagents containing a thioamide moiety, i.e. thioacetamide, benzylthiourea, symmetrical dialkyl- and diarylthioureas gave different cyclic products: 3,1-benzothiazine, 1,3,5-benzotriazocine and quinazoline. The reaction pathways of prepared compounds are discussed.
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