Voltammetrie 3-(azidomethylen)dihydrofuran-2-onu

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Title in English	Voltammetry of 3-(azidomethylene)dihydrofuran-2-one
Authors	ADAM Vojtěch FALTÝSKOVÁ Eva SOUKENÍKOVÁ Natália KIZEK René MAZAL Ctibor TRNKOVÁ Libuše
Year of publication	2002
Type	Article in Proceedings
Conference	Sborník abstrakt III. pracovního setkání fyzikálních chemiků a elektrochemiků v Brně
MU Faculty or unit	Faculty of Science
Citation
Field	Electrochemistry
Keywords	Cyklická diferenční pulzní square wave voltametrie;azidosloučeniny;redukce azidů
Description	The reduction of 3-(azidomethylene)dihydrofuran-2-one (AZMDF) was studied by voltammetric methods. The peak height and peak potential are dependent on various experimental conditions (pH, scan rate, time of accumulation). According to the scan rate coefficient it has been considered that the reduction process of azide group is controlled by diffusion. The difference of reduction peak potentials between (E) a (Z) forms (about 100 mV) it is possible to determine these azides in their mixtures. The best current signals with optimal separation of two peaks were observed in borate buffer.
Related projects:	Structure and character of bonding, properties and analysis of synthetic and natural molecular ensembles