Voltammetrie 3-(azidomethylen)dihydrofuran-2-onu

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Title in English Voltammetry of 3-(azidomethylene)dihydrofuran-2-one
Authors

ADAM Vojtěch FALTÝSKOVÁ Eva SOUKENÍKOVÁ Natália KIZEK René MAZAL Ctibor TRNKOVÁ Libuše

Year of publication 2002
Type Article in Proceedings
Conference Sborník abstrakt III. pracovního setkání fyzikálních chemiků a elektrochemiků v Brně
MU Faculty or unit

Faculty of Science

Citation
Field Electrochemistry
Keywords Cyklická diferenční pulzní square wave voltametrie;azidosloučeniny;redukce azidů
Description The reduction of 3-(azidomethylene)dihydrofuran-2-one (AZMDF) was studied by voltammetric methods. The peak height and peak potential are dependent on various experimental conditions (pH, scan rate, time of accumulation). According to the scan rate coefficient it has been considered that the reduction process of azide group is controlled by diffusion. The difference of reduction peak potentials between (E) a (Z) forms (about 100 mV) it is possible to determine these azides in their mixtures. The best current signals with optimal separation of two peaks were observed in borate buffer.
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