New fused heterocycles by combined intra-intermolecular criss-cross cycloaddition of nonsymmetrical azines

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Authors

MAN Stanislav KULHÁNEK Petr POTÁČEK Milan NEČAS Marek

Year of publication 2002
Type Article in Periodical
Magazine / Source Tetrahedron Letters
MU Faculty or unit

Faculty of Science

Citation
Field Organic chemistry
Keywords criss-cross cycloaddition; 1;3-dipolar; nonsymmetrical azine; 1;3;10-triazatricyklo[5.2.1.04;10]dec-6-en-2-one
Description Thermally induced intra-intermolecular criss-cross cycloaddition of nonsymmetrical azines in the presence of phenyl isocyanate is described. This one-pot reaction gives heterocyclic compounds containing three fused five-membered rings. The molecular and crystal structure of products is reported and discussed.
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