Reakce oxidu selenového s dialkylethery

Warning

This publication doesn't include Faculty of Arts. It includes Faculty of Science. Official publication website can be found on muni.cz.
Title in English The Reaction of Selenium Trioxide with Dialkyl Ethers
Authors

RICHTERA Lukáš TOUŽÍN Jiří

Year of publication 2002
Type Article in Proceedings
Conference Chemické listy
MU Faculty or unit

Faculty of Science

Citation
Field Inorganic chemistry
Keywords DA-complex; Selenium trioxide; Dialkyl ethers; Crystal structure; Raman spectra; 77Se NMR spectra
Description The donor-acceptor complexes Et2O.SeO3 and (Me2O)2.SeO3 can be obtained as primary products by the reactions of selenium trioxide with dimethyl ether (Me2O) and diethyl ether (Et2O). The crystal and molecular structure of both complexes with different stoichiometry SeO3.Et2O and SeO3.2Me2O respectively, which are stable below their melting points only, was determined by X-ray structure analysis. Conversion of the adducts to dialkylesters of diselenic and selenic acid in the liquid phase was monitored by Raman, 1H- and 77Se-NMR spectroscopy.
Related projects:

You are running an old browser version. We recommend updating your browser to its latest version.