Synthesis and Chemical Properties of Halogenophosphates
| Authors | |
|---|---|
| Year of publication | 2002 |
| Type | Article in Proceedings |
| Conference | Sborník příspěvků IV. seminář Pokroky v anorganické chemii |
| MU Faculty or unit | |
| Citation | |
| Field | Inorganic chemistry |
| Keywords | Diphosphoryl tetrafluoride; dichlorophosphate; chlorofluorophosphate; 1;1-difluoro-2-chlorodiphosphate; 1;1;2-trifluorodiphosphate; 1;1;3;3-tetrafluorotriphosphate |
| Description | The systematic study of the synthetic methods and structures of halogenophosphates enabled the succesfull preparations of tetraphenylphosphonium dichlorophosphate and 1,1,3,3-tetrafluorotriphosphate,which constitution was confirmed by X-ray crystal structure analysis.In addition,also the pure solid PPh4[PO2ClF] was isolated and the formation of 1,1,2-trifluorodiphosphate and 1,1,-difluoro-2-chlorodiphosphate could be revealed by 19F and 31P NMR spectroscopy. |
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