Reaction in The Solid State. Isomerization of N-Acylselenoureas into N-Acylisoselenoureas

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Authors

PAZDERA Pavel ŠIBOR Jiří MAREK Jaromír

Year of publication 2003
Type Article in Proceedings
Conference Proceedings of ECSOC-7, The Seventh International Electronic Conference on Synthetic Organic Chemistry, http://www.mdpi.org/ecsoc-7.htm, September 1-30, 2003. Editors: Julio A. Seijas, De-Chun Ji and Shu-Kun Lin. CD-ROM edition
MU Faculty or unit

Faculty of Science

Citation
Web http://www.mdpi.org/ecsoc-7.htm
Field Organic chemistry
Keywords Solid state; isomerization; selenoureas; isoselenoureas
Description Observation that some ethyl-2-(3-acylselenoureido)thiophen-3-carboxylates and their benzoanalogues undergo a photoisomerization to corresponding ethyl-2-(3-acylisoseleno-ureido)thiophen-3-carboxylates or appropriate benzoates into solid state is clarified on the base of X-ray structural analysis of some starting substances and quantum chemistry calculations for both types of compounds.
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