Preparation of Monomeric LAl(NH2)2 The First Main-Group Metal Diamide Containing Two Terminal NH2 Groups in the Presence of a N-heterocyclic Carbene as HCl Acceptor

Warning

This publication doesn't include Faculty of Arts. It includes Faculty of Science. Official publication website can be found on muni.cz.

Authors	JANCIK Vojtech PINEDA Leslie W. PINKAS Jiri ROESKY Herbert W. NECULAI Dante NECULAI Ana M. HERBST-IRMER Regine
Year of publication	2004
Type	Article in Periodical
Magazine / Source	Angewandte Chemie International Edition
MU Faculty or unit	Faculty of Science
Citation
Field	Inorganic chemistry
Keywords	aluminum amides carbenes hydroxides
Description	We have presented a novel method for preparing aluminum amides and hydroxides from the corresponding chlorides. The main byproduct - N,N-di-tbutylimidazolium chloride - can be easily separated from the product by filtration and recycled to the free base. LAl(NH2)2 is to the best of our knowledge the first monomeric main-group metal diamide containing two terminal NH2 groups.
Related projects:	New Nonaqueous Routes to Phosphate, Silicate, Hybrid, and Oxide Materials