The synthesis and crystal structures of two-dimensional coordination polymers of Ph2P(O)-CH2CH2-P(O)Ph2 and Ph2P(O)-C5H3N-P(O)Ph2 with praseodymium
| Authors | |
|---|---|
| Year of publication | 2004 |
| Type | Article in Periodical |
| Magazine / Source | INORGANIC CHEMISTRY |
| MU Faculty or unit | |
| Citation | |
| Field | Inorganic chemistry |
| Keywords | lanthanide layered network coordination polymers |
| Description | Reactions of Pr(NO3)3 with Ph2P(O)-CH2CH2-P(O)Ph2 and Ph2P(O)-C5H3N-P(O)Ph2 yielded layered network coordination polymers with bidentate ligands spanning the lanthanide atoms in bridging fashion. The praseodymium cations with spacer ligands form two-dimensional building blocks assembling into either square grid or herringbone architecture. |
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