Polysulfonylamines. Bis-(methylsulfonamido) Sulfone, bis-(trifluoromethylsulfonamido) Sulfone, its Synthesis and Crystal Structure.
| Authors | |
|---|---|
| Year of publication | 2004 |
| Type | Article in Periodical |
| Magazine / Source | Acta Crystallographica Section C: Crystal Structure |
| MU Faculty or unit | |
| Citation | |
| Field | Inorganic chemistry |
| Keywords | Polysulfonylamines; molecular structure; crystal structure |
| Description | Bis(methylsulfamido) sulfone, SO2(NHSO2CH3)2 (1) is synthesized from imido-bis(sulfonylchloride) HN(SO2Cl)2 and bis(trimethylsilyl) methane CH2(Si(CH3)3)2 in trimethylchlorsilane solution. In the solid state there are two independent molecules linked by two N-H....O hydrogen bridges into infinite chains parallel to the b-axis. Bis(trifluoromethylsulfamido)sulfone, SO2(NHSO2CF3)2 (2) is formed by the reaction of trichlorophosphazo-sulfuryl trifuoromethane Cl3PNSO2CF3 with fluorosulfonic acid FSO3H. The molecules are bonded by bifurcated N-H....O bridges into infinite layers parallel to the [001] plane. |
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