Effect of composition changes on properties and defect structure of crystalline Sm-doped ZrO2

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Authors

HARTMANOVÁ Mária KUBEL František BURŠÍKOVÁ Vilma JERGEL M. NAVRÁTIL Vladislav LOMONOVA E. E. NAVRÁTIL Karel KUNDRACIK F. KOSTI I.

Year of publication 2007
Type Article in Periodical
Magazine / Source Russian Journal of Electrochemistry
MU Faculty or unit

Faculty of Science

Citation
Field Solid matter physics and magnetism
Keywords crystals;ZrO2;Sm2O3;polymorphous structure;pyrochlore phase;electrical conductivity;microhardness;elastic modulus;aborption coefficient;refractive index
Description Polymorphous structure, electrical conductivity, absorption coefficient, refractive index, and mechanical characteristics of crystalline system ZrO2 + x Sm2O3 is investigated. Vickers microhardness is investigated by the well-known quasi-static indentation method. Plastic microhardness and the effective elastic modulus are studied by the depth-sensing indentation technique. Special attention is devoted to the ordered defect fluorite structure, pyrochlore phase Sm2Zr2O7, observed for x = 43 mol %. Potential applications of the investigated system are discussed.
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