The synthesis and characterization of new aminoadamantane derivatives of hexachloro-cyclo-triphosphazene

Warning

This publication doesn't include Faculty of Arts. It includes Faculty of Science. Official publication website can be found on muni.cz.
Authors

KOČÍ VOZNICOVÁ Radka TARABA Jan PŘÍHODA Jiří ALBERTI Milan

Year of publication 2008
Type Article in Periodical
Magazine / Source Polyhedron
MU Faculty or unit

Faculty of Science

Citation
Field Inorganic chemistry
Keywords cyclo-Triphosphazene; 1-Aminoadamantane; Amantadine; Memantine; Crystal and molecular structure
Description The reactions of hexachloro-cyclo-triphosphazene P3N3Cl6 (1) with aminoadamantane (amantadine, Ad-NH2) and memantine were studied. New geminally substituted phosphazene derivatives, P3N3Cl4(NH-Ad)2 (2), P3N3Cl2(NH-Ad)4 (3) and P3N3Cl2(Mem)4 (4), were prepared. The substances 3 and 4 were fully characterized by 31P NMR and IR spectroscopies and elemental analysis. Molecular and crystal structures of 2,3,4 were determined by Xray diffraction. The compounds are triclinic, space group . Compound 3 crystallized from dichloromethane as a solvate.
Related projects:

You are running an old browser version. We recommend updating your browser to its latest version.