Photochemical synthesis of indan-1-ones via 2,5-dimethylphenacyl epoxides

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Authors

ŠOLOMEK Tomáš TAZHE VEETIL Aneesh KLÁN Petr

Year of publication 2009
Type Article in Proceedings
Conference Študentská vedecká konferencia
MU Faculty or unit

Faculty of Science

Citation
Web http://monet.fns.uniba.sk/svk2009/doc/zbornik_09.pdf
Keywords photochemistry;hydrogen atom abstraction;photoenolization;indanone;epoxides;synthesis;density functional theory
Description The work concerns with a new way of indan-1-one derivatives synthesis via a photochemical enolization followed by cyclization and epoxide ring opening of substituted 1-(o-methylphenyl)-2,3-epoxypropan-1-one moiety and also with mechanistic and theoretical studies of this transformation.
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