Metal Complexes of 4,11-Dimethyl-1,4,8,11-tetraazacyclotetradecane-1,8-bis(methylphosphonic acid) - Thermodynamic and Formation/Decomplexation Kinetic Studies

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Authors	SVOBODOVÁ Ivona HAVLÍČKOVÁ Jana PLUTNAR Jan LUBAL Přemysl KOTEK Jan HERMANN Petr
Year of publication	2009
Type	Article in Periodical
Magazine / Source	Eur. J. Inorg. Chem.
MU Faculty or unit	Faculty of Science
Citation
Web	http://dx.doi.org/10.1002/ejic.200900358
Field	Inorganic chemistry
Keywords	X-ray crystal structure; macrocyclic ligands; phosphonate complexes; copper(ii) complexes; cyclam derivatives; zinc(ii) complexes; cadmium(ii) complexes; complexation / decomplexation kinetics; radiopharmaceuticals
Description	Bis(phosphonic) acid derivative of cyclam was synthesized by an improved synthesis. Thermodynamic stability of divalent metal complexes was determined. Formation and decomplexation kinetics of complexes with divalent copper, zinc and cadmium was investigated.
Related projects:	Research of new detection systems based on sensor arrays for application in speciation analysis