KINETICKÉ STUDIUM CE(III) A CU(II) KOMPLEXŮ CYKLENOVÝCH DERIVÁTŮ S PENDANTNÍMI SKUPINAMI OBSAHUJÍCÍMI FOSFOR
Title in English | KINETIC STUDY OF CE(III) AND CU(II) COMPLEXES OF CYCLEN DERIVATIVES WITH PENDANT GROUPS CONTAINING PHOSPHORUS |
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Authors | |
Year of publication | 2009 |
Type | Article in Periodical |
Magazine / Source | CHEMICKÉ LISTY |
MU Faculty or unit | |
Citation | |
Field | Inorganic chemistry |
Keywords | macrocyclic ligands; phosphorus pendant arms; kinetics; Cu(II); Ce(III) |
Description | The disociation kinetics of Cu(II) a Ce(III) complexes was studied and it was shown that substitution of carboxylate pendant arm by phosponic group leads to higher kinetic inertness of Ce(III) complexes while opposite trend was found for Cu(II) complexes. |
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