KINETICKÉ STUDIUM CE(III) A CU(II) KOMPLEXŮ CYKLENOVÝCH DERIVÁTŮ S PENDANTNÍMI SKUPINAMI OBSAHUJÍCÍMI FOSFOR

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Title in English KINETIC STUDY OF CE(III) AND CU(II) COMPLEXES OF CYCLEN DERIVATIVES WITH PENDANT GROUPS CONTAINING PHOSPHORUS
Authors

ŠEVČÍK Radek LUBAL Přemysl

Year of publication 2009
Type Article in Periodical
Magazine / Source CHEMICKÉ LISTY
MU Faculty or unit

Faculty of Science

Citation
Field Inorganic chemistry
Keywords macrocyclic ligands; phosphorus pendant arms; kinetics; Cu(II); Ce(III)
Description The disociation kinetics of Cu(II) a Ce(III) complexes was studied and it was shown that substitution of carboxylate pendant arm by phosponic group leads to higher kinetic inertness of Ce(III) complexes while opposite trend was found for Cu(II) complexes.
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