SYNTHESIS OF A NOVEL 4H-BENZO[1.2.4]DITHIAZINE SYSTEM AND STUDIES OF ITS ELECTROCHEMICAL BEHAVIOUR
| Authors | |
|---|---|
| Year of publication | 2003 |
| Type | Article in Proceedings |
| Conference | Proceedings of ECSOC-7, The Seventh International Electronic Conference on Synthetic Organic Chemistry, http://www.mdpi.org/ecsoc-7.htm, September 1-30, 2003. Editors: Julio A. Seijas, De-Chun Ji and Shu-Kun Lin. CD-ROM edition |
| MU Faculty or unit | |
| Citation | |
| Web | http://www.mdpi.org/ecsoc-7.htm |
| Field | Organic chemistry |
| Keywords | 4H-BENZO[1.2.4]DITHIAZINE; redox ring opening-closure; cyclic voltametry |
| Description | Compounds containing the chalcogen-chalcogen bond (chalkogen can be sulphur and/or selenium) in molecules could be potential scavenger for free radicals in organisms, because the bond chalcogen-chalcogen may be liable to the reversible redox bond-opening and bond-closure. Now we found a facile method for preparation of the new benzo[1,2,4]dithiazine skeleton containig -S-S- moiety into molecule. Electrochemical studies show the reversible redox ring-opening and ring-closure on S-S bond of skeleton. |
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