The Electrodeless Discharge Lamp: A Prospective Tool for Photochemistry Part 6: Photochemistry of Valerophenone and 4-Nitroanisole in High-Temperature Water
| Název česky | Fotochemie valerofenonu a nitroanisolu v peháté vod |
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| Autoři | |
| Rok publikování | 2005 |
| Druh | Článek v odborném periodiku |
| Časopis / Zdroj | Journal of Photochemistry and Photobiology A: Chemistry |
| Fakulta / Pracoviště MU | |
| Citace | |
| Obor | Organická chemie |
| Klíčová slova | Photochemistry; Microwave; Electrodeless discharge lamp; High-temperature water; Valerophenone |
| Popis | Two temperature-sensitive model photochemical reactions, the Norrish Type II reaction and photochemical nucleophilic aromatic substitution on 4-nitroanisole by the hydroxide ion, carried out in high-temperature water (100-200 oC) in a pressurized vessel under microwave heating, are reported. The observed chemoselectivity and the ability to increase the solubility of hydrophobic organic compounds in this environmentally friendly solvent are promising results for prospective green (photo)chemical applications. |
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